(PDF) Optical Outer-Sphere Metal to Metal Charge Transfer

Optical Outer-Sphere Metal to Metal Charge Transfer in the Ion Pairs [Pt(NH3)5Cl]3+[M(CN)6]4− With M = Fe, Ru and Os

Inorganica Chimica Acta - Netherlands

doi 10.1016/s0020-1693(00)87615-x

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Date

October 1, 1988

Authors

Arnd Vogler

Horst Kunkely

Publisher

Elsevier BV

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Optical Outer-Sphere Metal to Metal Charge Transfer in the Ion Pairs [Pt(NH3)5Cl]3+[M(CN)6]4− With M = Fe, Ru and Os

Inorganica Chimica Acta - Netherlands

doi 10.1016/s0020-1693(00)87615-x

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Abstract

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Nuclear Magnetic Resonance Studies on the Anions [M(SnCl3)5Cl]4−(M = Ru, Os) and [Ru(SnCl3)5(MeCN)]3−: The X-Ray Crystal Structure of [N(C2H5)4]4[Ru(SnCl3)5Cl]

Exothermal Effect in the Thermal Decomposition of [IrCl6]2- Containing Salts With [M(NH3)5Cl]2+ Cations: [M(NH3)5Cl][IrCl6] (М = Co, Cr, Ru, Rh, Ir)

Molecular Deformation, Charge Flow, and Spongelike Behavior in Anion-Π {[M(CN)4 ]2− ;[HAT(CN)6 ]}∞ (M=Ni, Pd, Pt) Supramolecular Stacks

Molecular Deformation, Charge Flow, and Spongelike Behavior in Anion-Π {[M(CN)4 ]2− ;[HAT(CN)6 ]}∞ (M=Ni, Pd, Pt) Supramolecular Stacks

Inner and Outer Sphere Perturbation of the Ru(III)-Cyanamide Bond and the Consequences to Metal-Metal Coupling.

Cs2Zn(CN)4: A First Example of a Non-Cyano Spinel of Composition A2M(CN)4 With A=alkali Metal and M=group 12 Metal

M2(m-Dobdc) (M = Mg, Mn, Fe, Co, Ni) Metal–Organic Frameworks Exhibiting Increased Charge Density and Enhanced H2Binding at the Open Metal Sites

Induced Optical Activity in Co(NH3)6(3+) and Co(en)3(3+) Upon Outer-Sphere Association With (+)-Tartarate2- And Other Chiral Anions.

Double Complex Salts With [Ru(NH3)5Cl]2+cation and [OsCl6]2−anion: Synthesis and Properties. Crystal Structure of the [Ru(NH3)5Cl]2[OsCl6]Cl2