SYNTHESIS AND RESOLUTION OF a NEW TYPE OF CHIRAL BISPHOSPHINE LIGAND,trans-BIS-1,2-(DIPHENYLPHOSPHINO)CYCLOBUTANE, AND ASYMMETRIC HYDROGENATION USING ITS RHODIUM COMPLEX

Chemistry Letters- Japan

doi 10.1246/cl.1986.613

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April 5, 1986

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The Chemical Society of Japan

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SYNTHESIS AND RESOLUTION OF a NEW TYPE OF CHIRAL BISPHOSPHINE LIGAND,trans-BIS-1,2-(DIPHENYLPHOSPHINO)CYCLOBUTANE, AND ASYMMETRIC HYDROGENATION USING ITS RHODIUM COMPLEX

Chemistry Letters- Japan

Full Text

Abstract

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Date

Authors

Publisher

Related search

2,2'-Dimethyl-6,6'-Bis(diphenylphosphino)biphenyl (BIPHEMP) as a Chiral Ligand for Transition Metal Catalyzed Asymmetric Synthesis of Binaphthyls and for Asymmetric Hydrogenation. A Comparison With BINAP.

Chiral Rhodium Complex-Catalyzed Asymmetric Cyclization and Its Application to the Synthesis of Natural Products.

Asymmetric Reactions Catalyzed by Chiral Metal Complexes. XXXVIII. Efficient Asymmetric Hydrogenation of (Z)-2-Acetamidocinnamic Acid Catalyzed by the Rhodium Complex of Modified N-Benzyl-(3r,4r)-3,4-Bis(diphenylphosphino)pyrrolidine (Degphos).

Formation of a Stable Rhodium Dihydride Complex and Its Reactions With Prochiral Substrates of Asymmetric Hydrogenation

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