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Transient Palladadiphosphanylcarbenes: Singlet Carbenes With an Inverse Electronic Configuration (Pp2 Instead of S2) and Unusual Transannular Metal-Carbene Interactions (pCfPd Donation and sPdfC Back-Donation)
doi 10.1021/ja066738j.s001
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American Chemical Society (ACS)
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Transient Palladadiphosphanylcarbenes: Singlet Carbenes With an “Inverse” Electronic Configuration (Pπ2instead of Σ2) and Unusual Transannular Metal−Carbene Interactions (πC→PdDonation and σPd→CBack-donation)
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