Transient Palladadiphosphanylcarbenes: Singlet Carbenes With an “Inverse” Electronic Configuration (Pπ2instead of Σ2) and Unusual Transannular Metal−Carbene Interactions (πC→PdDonation and σPd→CBack-donation)

Journal of the American Chemical Society - United States
doi 10.1021/ja066738j
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American Chemical Society (ACS)

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